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- W2019919264 abstract "Diels-Alder reactions of the acrylate of (S)-ethyl lactate with cyclopentadiene proceed with diastereoface-selectivity of up to 85:15 (non-catalyzed) and 93:7 (TiCl4-promoted). Depending on the Lewis acid, products of inverse configuration are obtained. In conjunction with facile product analysis by LC, effective means for suppression of polymerization of the diene, and virtually epimerization-free ester hydrolysis these findings constitute a method for large scale practical applications of the asymmetric Diels-Alder reaction." @default.
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- W2019919264 date "1984-01-01" @default.
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- W2019919264 title "Influence of polar groups in thermal and Lewis acid promoted asymmetric diels-alder additions: lactic acid derivatives as practical highly selective and configurationally dichotomic reagents" @default.
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- W2019919264 doi "https://doi.org/10.1016/s0040-4039(01)80207-0" @default.
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