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- W2019920281 abstract "The long-range interaction energy between two like atoms in different energy states is discussed in general, through O (α2), using the Breit-Pauli approximation. Selection rules are derived for possible interactions where retardation or relativistic effects may be important. The S-P resonant interaction is considered as a specific example. The interaction energies for the resulting Σ and Π molecular states are calculated in both the Breit-Pauli approximation and from the exact dipole-dipole results of McLone and Power, Stephen and others. The R−1 expansion of the exact result and the validity of the Breit-Pauli approximation are discussed in detail. The interaction energies are also compared with the linewidths for the various molecular states. It is shown that the Breit-Pauli approximation can give a good representation (especially for the Σ states) of the interaction for quite large values of R <̃ λ, where λ is the characteristic wavelength for the S-P transition." @default.
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- W2019920281 date "1968-01-01" @default.
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- W2019920281 title "Retarded Interaction Energies between Like Atoms in Different Energy States" @default.
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- W2019920281 doi "https://doi.org/10.1063/1.1667907" @default.
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