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- W2019920510 abstract "The hysteresis effects of fluids confined in porous media are studied by means of a new microscopic model. We consider a slitlike pore of infinite area and finite height. In contrast to the unbounded parallel-plate case, the new model allows the formation and the disappearance of curved menisci at the open ends of the pore. This effect has a profound influence on the extent of the hysteresis loops. On the other hand, we find that the presence of the menisci does not play a significant role in locating the equilibrium first-order transition in long pores. The present treatment reconciles the traditional picture of capillary condensation with the modern microscopic treatment based on the density-functional formalism." @default.
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- W2019920510 date "1989-04-01" @default.
- W2019920510 modified "2023-09-24" @default.
- W2019920510 title "Microscopic model for hysteresis and phase equilibria of fluids confined between parallel plates" @default.
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- W2019920510 doi "https://doi.org/10.1103/physreva.39.4109" @default.
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