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- W2019920516 abstract "Cation fluxes were determined for various three-component, equimolar mixtures of alkali metal, alkaline earth, and Pb2+ cations in a H2OCHCl3H2O liquid membrane system incorporating macrocyclic polyethers as carriers. Carrier ligands studied were 18-crown-6, dicyclohexano-18-crown-6, 1,10-diaza-18-crown-6, 21-crown-7, dibenzo-24-crown-8, and cryptand [2.2.2]. Correlations were found between transport and relative cation:polyether cavity radii, the type of substituents present on the polyether ring, and the type and number of donor atoms present. All the ligands studied transported Pb2+ at higher rates than the other Mn+ in the mixtures. Transport behavior in these multi-cation systems can be predicted from Mn+—polyether complex stability constant data in most cases." @default.
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- W2019920516 date "1984-09-01" @default.
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- W2019920516 title "Facilitated transport from ternary cation mixtures through water—chloroform—water membrane systems containing macrocyclic ligands" @default.
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- W2019920516 doi "https://doi.org/10.1016/s0376-7388(00)82004-9" @default.
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