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• W2019920617 abstract "A novel strategy for the immobilization of cytochrome c on the surface of chemically modified electrodes is demonstrated and used to investigate the protein's electron-transfer kinetics. Mixed monolayer films of alkanethiols and omega-terminated alkanethiols (terminated with pyridine, imidazole, or nitrile groups that are able to ligate with the heme) are used to adsorb cytochrome c to the surface of gold electrodes. The use of mixed films, as opposed to pure films, allows the concentration of adsorbed cytochrome to remain dilute and ensures a higher degree of homogeneity in their environment. The adsorbed protein is studied using electrochemical methods and scanning tunneling microscopy." @default.
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• W2019920617 date "2002-07-17" @default.
• W2019920617 modified "2023-10-02" @default.
• W2019920617 title "Direct Wiring of Cytochrome <i>c</i>'s Heme Unit to an Electrode: Electrochemical Studies" @default.
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• W2019920617 doi "https://doi.org/10.1021/ja025518c" @default.
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