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- W2019921777 abstract "Starting from (S)-(−)-α-(2-pyridyl)ethylamine, 11 new multidentate ligands were prepared and characterized. Reaction with [Rh(cod)Cl]2 yielded the (cyclooctadiene)(imine)-RhI complexes (I–VII). The isolated complexes and the in-situ systems [Rh(cod)Cl]2/1–11 were used as enantioselective catalysts in the hydrosilylation of acetophenone with diphenylsilane. The resulting α-phenylethanol was found to have an optical purity of up to 35.2% ee. Ausgehend von (S)-(−)-α-(2-Pyridyl)ethylamin wurden 11 neue mehrzähnige Liganden dargestellt und charakterisiert. Dutch Umsetzung mit [Rh(cod)Cl]2 wurden die (Cyclooctadien)(Imin)-RhI-Komplexe (I–VII) erhalten. Die isolierten Komplexe und die In-situ-Systeme [Rh(cod)Cl]2/1–11 wurden als enantioselektive Katalysatoren in die Hydrosilylierung von Acetophenon mit Diphenylsilan eingesetzt. Das entstehende α-Phenylethanol hat eine optische Reinheit bis zu 35.2% ee." @default.
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- W2019921777 date "1987-11-01" @default.
- W2019921777 modified "2023-09-25" @default.
- W2019921777 title "Asymmetrische katalysen XXXVI. Neue mehrzähnige liganden mit dem (S)-(α)-(2-Pyridyl)ethylrest; Rh-komplexe und enantioselektive hydrosilylierungen" @default.
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- W2019921777 doi "https://doi.org/10.1016/0022-328x(87)85169-0" @default.
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