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- W2019922099 abstract "N -Octylamides of diastereomeric gluconic and gulonic acids form molecular aggregates of extremely different curvature, namely helical micellar rods with a diameter of 4 nm and planar bilayers. In the crystal structure of the gulonamide compound, symmetric “tail-to-tail” bilayer sheets are observed, whereas the gluconamide derivative (whose crystal structure was determined previously) forms an unusual “head-to-tail” arrangement. These differences are unexpected because both diastereomers contain one pair each of syn - and anti -oriented hydroxyl groups in 1,3-positions of the extended aldonic acid chains. The experimental results are explained by the occurrence of hydrogen-bond patterns between hydroxyl groups, either within one crystal sheet or hydrophobic bilayer (gluconamide) or between the end groups of neighboring sheets (gulonamide)." @default.
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- W2019922099 date "1992-06-01" @default.
- W2019922099 modified "2023-10-17" @default.
- W2019922099 title "The crystal packing of N-(n-octyl)-d-gulonamide containing tail-to-tail sheets compared to its gluconamide diastereomer showing head-to-tail arrangement" @default.
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- W2019922099 doi "https://doi.org/10.1016/s0008-6215(00)90511-1" @default.
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