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• W2019924147 abstract "Three new caged nitric oxides (NOs)-BNN3, BNN5Na, and BNN5M were tested for biological use. BNNs have a strong ultraviolet (UV) absorption band (lambda(max): 300 nm, epsilon: 13.5 mM(-1) cm (-1)) extended to 420 nm and produce NO upon irradiation with 300-360 nm light in quantum yields about 2. A photoexcited BNN molecule yields two NOs with time constants of less than 10 ns for phase 1 and less than 20 micros for phase 2 at 37 degrees C, suggesting usefulness of BNNs for measuring in vivo and in vitro fast NO reactions. Upon irradiating with UV light, caged nitric oxides-loaded rat aortic strips maintained in a state of active tonic contraction effectively relaxed ( < 3 microM BNN5M loading solution concentration). BNN3 is incorporated in the lipid membrane. BNN5Na, insoluble in organic solvents but water soluble, localizes in the water phase. BNN5M, is muscle-cell-permeable and hydrolysed to BNN5Na to remain in cytosol. BNNs were thermally stable and demonstrated no observable toxicity." @default.
• W2019924147 created "2016-06-24" @default.
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• W2019924147 date "1999-08-01" @default.
• W2019924147 modified "2023-09-27" @default.
• W2019924147 title "Bis- N -nitroso-caged nitric oxides: photochemistry and biological performance test by rat aorta vasorelaxation" @default.
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• W2019924147 doi "https://doi.org/10.1016/s0968-0896(99)00084-x" @default.
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