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- W2019928851 abstract "In this work, a multiwall carbon nanotubes modified electrode (prepared by incorporating TiO 2 nanoparticles with p ‐aminophenol as a mediator) was used as voltammetric sensor for the determination of 6‐mercaptopurine (6‐MP) in the presence of uric acid (UA). The voltammograms of 6‐MP and UA in a mixture can be separated from each other by differential pulse voltammetry with a potential difference of 380 mV at a scan rate of 10 mV s −1 . These conditions are sufficient to allow for the determination of 6‐MP and UA both individually and simultaneously. The electrocatalytic currents increase linearly with 6‐MP concentration in the ranges of 0.09–350 µmol L −1 (two linear segments with different slopes). The detection limit for 6‐MP was 0.065 µmol L −1 . The RSD% for 1.0 and 15.0 µmol L −1 6‐MP were 0.7%, and 1.2%, respectively. The kinetic parameters of the system were determined using electrochemical approaches. The method was successfully applied for the determination of 6‐MP in drug sample, and 6‐MP plus UA in urine samples. Copyright © 2011 John Wiley & Sons, Ltd." @default.
- W2019928851 created "2016-06-24" @default.
- W2019928851 creator A5028477000 @default.
- W2019928851 creator A5088287584 @default.
- W2019928851 date "2011-05-03" @default.
- W2019928851 modified "2023-10-03" @default.
- W2019928851 title "Determination of 6-mercaptopurine in the presence of uric acid using modified multiwall carbon nanotubes-TiO<sub>2</sub>as a voltammetric sensor" @default.
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- W2019928851 doi "https://doi.org/10.1002/dta.286" @default.
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