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- W2019930480 abstract "The purpose of the research was to establish whether the water configurations, detected by previous differential scanning calorimetry (DSC) analysis, could give rise to different or characteristic nuclear magnetic resonance relaxations. We report the results of a study on water–hexadecane microemulsions at different water contents. The 1 H spin–spin and spin–lattice relaxation curves were obtained at 20 MHz and 310 K. The trends of all best-fit relaxation parameters versus water concentration were compared with those obtained for D 2 O microemulsions with the same experimental conditions and fitting procedures. Two different H 2 O microemulsion states were identified: (i) all the systems without free water (defined by DSC as water melting at 273 K) were characterized by 1 H spin–spin and spin–lattice relaxation curves well described by two exponential functions and (ii) all the systems with free water were characterized by relaxation curves well described by three exponential functions. The identification of the main phases of the microemulsions interphasal region and continuous medium, besides free water, seems possible on the basis of the 1 H magnetic relaxation characteristics." @default.
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- W2019930480 date "1990-09-01" @default.
- W2019930480 modified "2023-09-26" @default.
- W2019930480 title "Different degrees of hydration in water–oil microemulsions by low-resolution 1H magnetic relaxation analysis" @default.
- W2019930480 doi "https://doi.org/10.1139/p90-147" @default.
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