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• W2019931575 abstract "(R,R)-(+)-2-[Benzyl-(2-hydroxy-2-phenylethyl)amino]-1-phenylethanol 1 is used as a chiral ligand in the synthesis of an optically active lanthanum–sodium amino diol complex LS-1. This heterobimetallic catalyst is quite effective as an asymmetric catalyst for various Michael addition reactions, 1H NMR study indicates the co-ordination of enone to the central lanthanum atom in LS-1. The reaction conditions were optimized and the adducts were obtained in high yield with moderate to high enantiomeric excess under extremely mild conditions." @default.
• W2019931575 created "2016-06-24" @default.
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• W2019931575 date "2002-06-01" @default.
• W2019931575 modified "2023-10-09" @default.
• W2019931575 title "Asymmetric Michael addition reactions using a chiral La–Na aminodiolate catalyst" @default.
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• W2019931575 doi "https://doi.org/10.1016/s0957-4166(02)00240-9" @default.
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