Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019933599> ?p ?o ?g. }
- W2019933599 endingPage "2972" @default.
- W2019933599 startingPage "2972" @default.
- W2019933599 abstract "The sterically encumbered 1,2,4-(Me3C)3C5H2 (Cp′) ligand allows the synthesis of stable high spin mono(cyclopentadienyl) manganese complexes [Cp′MnX(thf)]2 (X = Cl, Br, I; 1-X). Thermal stabilities of 1-X toward ligand redistribution to [Cp2′Mn] (2) and MnX2 depend on the bridging halide ligand. The kinetic stability of 1-I in solution even at elevated temperatures is noteworthy. Complexes 1 are useful starting materials for further functionalizations. Metathesis of 1-Cl with [LiN(SiMe3)2(OEt2)]2 yields the 13 valence-electron (VE) complex, [Cp′MnN(SiMe3)2] (3), while the manganese polyhydride cluster, [{Cp′Mn}4{MnH6}], was formed in the reaction of 1-I and KHBEt3. The 17 VE [MnH6]4− core of 4 is effectively shielded by four high spin [Cp′Mn]+ units. Magnetic susceptibility studies on 4 suggest weak electron exchange coupling between the spin carriers, but the spin state of the central [MnH6]4− fragment remained ambiguous. Therefore, the electronic structure of 4 was also analyzed by broken symmetry (BS) DFT calculations, which provided strong evidence for a low spin [MnH6]4− unit in agreement with previous spectrochemical studies performed on [FeH6]4−." @default.
- W2019933599 created "2016-06-24" @default.
- W2019933599 creator A5010213141 @default.
- W2019933599 creator A5034751002 @default.
- W2019933599 creator A5041623914 @default.
- W2019933599 creator A5046820685 @default.
- W2019933599 creator A5061302621 @default.
- W2019933599 creator A5078626568 @default.
- W2019933599 creator A5089476171 @default.
- W2019933599 date "2012-01-01" @default.
- W2019933599 modified "2023-10-16" @default.
- W2019933599 title "Reactivity studies on [Cp′MnX(thf)]2: manganese amide and polyhydride synthesis" @default.
- W2019933599 cites W1964069488 @default.
- W2019933599 cites W1965159913 @default.
- W2019933599 cites W1970306721 @default.
- W2019933599 cites W1970990568 @default.
- W2019933599 cites W1971038878 @default.
- W2019933599 cites W1971148520 @default.
- W2019933599 cites W1972844879 @default.
- W2019933599 cites W1975319963 @default.
- W2019933599 cites W1977836395 @default.
- W2019933599 cites W1978061267 @default.
- W2019933599 cites W1983530472 @default.
- W2019933599 cites W1984170182 @default.
- W2019933599 cites W1990139138 @default.
- W2019933599 cites W1991156790 @default.
- W2019933599 cites W1992074406 @default.
- W2019933599 cites W1994178208 @default.
- W2019933599 cites W1997740585 @default.
- W2019933599 cites W2000466466 @default.
- W2019933599 cites W2001697297 @default.
- W2019933599 cites W2006467903 @default.
- W2019933599 cites W2010560917 @default.
- W2019933599 cites W2011892869 @default.
- W2019933599 cites W2016573565 @default.
- W2019933599 cites W2019141695 @default.
- W2019933599 cites W2019273763 @default.
- W2019933599 cites W2020783584 @default.
- W2019933599 cites W2022796113 @default.
- W2019933599 cites W2022887974 @default.
- W2019933599 cites W2024382121 @default.
- W2019933599 cites W2025744260 @default.
- W2019933599 cites W2026802358 @default.
- W2019933599 cites W2027548849 @default.
- W2019933599 cites W2036647980 @default.
- W2019933599 cites W2038305447 @default.
- W2019933599 cites W2041897994 @default.
- W2019933599 cites W2045297606 @default.
- W2019933599 cites W2045952721 @default.
- W2019933599 cites W2046120957 @default.
- W2019933599 cites W2049188729 @default.
- W2019933599 cites W2051478613 @default.
- W2019933599 cites W2051734422 @default.
- W2019933599 cites W2055230539 @default.
- W2019933599 cites W2056462855 @default.
- W2019933599 cites W2058210956 @default.
- W2019933599 cites W2058353514 @default.
- W2019933599 cites W2058709770 @default.
- W2019933599 cites W2061851313 @default.
- W2019933599 cites W2066746249 @default.
- W2019933599 cites W2070074412 @default.
- W2019933599 cites W2071475415 @default.
- W2019933599 cites W2072271076 @default.
- W2019933599 cites W2072940337 @default.
- W2019933599 cites W2074065308 @default.
- W2019933599 cites W2074100780 @default.
- W2019933599 cites W2074869166 @default.
- W2019933599 cites W2076191524 @default.
- W2019933599 cites W2082529064 @default.
- W2019933599 cites W2082719796 @default.
- W2019933599 cites W2086957099 @default.
- W2019933599 cites W2089359208 @default.
- W2019933599 cites W2104230868 @default.
- W2019933599 cites W2106804342 @default.
- W2019933599 cites W2111826641 @default.
- W2019933599 cites W2117728207 @default.
- W2019933599 cites W2119547517 @default.
- W2019933599 cites W2119567217 @default.
- W2019933599 cites W2122011827 @default.
- W2019933599 cites W2134702028 @default.
- W2019933599 cites W2134963558 @default.
- W2019933599 cites W2141414702 @default.
- W2019933599 cites W2143981217 @default.
- W2019933599 cites W2148800508 @default.
- W2019933599 cites W2156641253 @default.
- W2019933599 cites W2167590372 @default.
- W2019933599 cites W2171135806 @default.
- W2019933599 cites W2321412785 @default.
- W2019933599 cites W2321699552 @default.
- W2019933599 cites W2332852929 @default.
- W2019933599 cites W273813344 @default.
- W2019933599 cites W2950924975 @default.
- W2019933599 cites W2951590798 @default.
- W2019933599 cites W2951822511 @default.
- W2019933599 cites W2952082225 @default.
- W2019933599 cites W2952232368 @default.
- W2019933599 cites W37839289 @default.
- W2019933599 cites W4211095161 @default.