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- W2019935285 abstract "The heat of reaction for addition of iodine to the planar complexes RhCl(CO)dppe, Rh(dppen)2+, Rh(dppe)2+ and to the dimer Rh2Cl2(CO)2(dppm)2 has been obtained by a calorimetric method. Iodine forms stronger RhI bonds with RhCl(CO)dppe than with the bichelate complexes. The presence of metal-metal interaction in the iodine addition compound of Rh2Cl2(CO)2(dppm)2 makes a significant contribution to the enthalpy change for the oxidative addition. The stereochemistry of the complexes are discussed on the basis of IR and 31P NMR spectra." @default.
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- W2019935285 date "1982-12-01" @default.
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- W2019935285 title "Enthalpy changes in oxidative addition reactions of iodine with monomeric and dimeric rhodium(I) complexes" @default.
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- W2019935285 doi "https://doi.org/10.1016/s0022-328x(00)85147-5" @default.
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