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- W2019935306 abstract "Reaction of chloroform with ketone enol eters 1d,e carried out in the presence of 50% aq NaOH and benzyltriethylammonium chloride (TEBAC) as a catalyst gives gem-dichlorocyclopropanes 3d,e. In the case of enol esters of aldehydes, adducts of trichloromethyl anion 2a,b,f,h (from 1a,b,f,h) or mixtures of 2 and 3 (from 1c,g,i) are formed. the same reaction carried out with a catalytic amount of tetramethylammonium hydrogen sulphate (TMAHS) yields mixtures of 2 and 3, highly enriched in the latter products, or pure 3i from 1i. The kind of the products formed depends on ease of cleavage of 1 by base, nucleophilicity of carboncarbon double bond in 1, and type of the catalyst applied." @default.
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- W2019935306 date "1997-01-01" @default.
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- W2019935306 title "Phase transfer catalyzed (PTC) reactions of chloroform with alkenyl carboxylates. Effect of catalyst structure on reaction course" @default.
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- W2019935306 doi "https://doi.org/10.1016/s0040-4020(96)01029-0" @default.
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