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- W2019936678 abstract "High molecular weight poly(l-β-3,4-dihydroxyphenyl-α-alanine) has been synthesized. Both optical rotatory dispersion and circular dichroism spectra of the polypeptide are anomalous and give little information about its conformation. From the total results obtained by a study of the optical rotation, nuclear magnetic resonance and infra-red absorption, poly(l-β-3,4-dihydroxyphenyl-α-alanine) is most probably right-handed helical in trimethyl phosphate, methanol or water/trimethyl phosphate (1:1 vv) mixed solvents below pH 10.4. It is in the random coil structure in dimethyl sulphoxide or water/trimethyl phosphate mixed solvents above pH 11. The transition midpoint is pH 10.6 in water/trimethyl phosphate mixed solvents. The results were compared with those of poly(l-tyrosine)." @default.
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- W2019936678 date "1977-10-01" @default.
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- W2019936678 title "Synthesis and conformational study of poly(l-β-3,4-dihydroxyphenyl-α-alanine)" @default.
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- W2019936678 doi "https://doi.org/10.1016/0032-3861(77)90001-5" @default.
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