FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019938129> ?p ?o ?g. }

• W2019938129 endingPage "219" @default.
• W2019938129 startingPage "199" @default.
• W2019938129 abstract "Deposition of a monolayer of titanium on the TiO2(100)-( 1 × 3) single crystal surface produces an oxygen deficient surface which has the same chemical composition, electronic structure and chemical reactivity as the Ar ion sputtered TiO2(100) surface. From correlations with studies of oxidation of the Ti(0001) single crystal surface, we provide firm evidence for the existence of Ti+3 species on the clean oxygen deficient TiO2 surface. The chemisorption of O2, H2 and H2O has been studied by ultraviolet photoemission spectroscopy (UPS), electron energy loss spectroscopy (ELS), Auger electron spectroscopy (AES), low-energy electron diffraction (LEED) and thermal desorption on the stoichiometric and Ti+3-rich TiO2(100) surfaces. The presence of surface Ti+3 species causes distinct differences in the nature of chemical bonding between the adsorbed molecule and the substrate surface. From the combination of these studies, we conclude that water is adsorbed associatively on the stoichiometric TiO2(100)−( 1 × 3) surface while it tends to dissociate into surface hydroxyl groups on the Ti+3 rich surface. UPS and ELS show that while adsorption of H2O changes the Ti+3 to a different oxidation state, illumination by band gap energy photons can regenerate Ti+3 species by the reaction Ti+4 + e− → Ti+3. An attempt has been made to correlate these results on well characterized surfaces with studies using TiO2 as a photoanode in the photo-electrochemical cell." @default.
• W2019938129 created "2016-06-24" @default.
• W2019938129 creator A5051920789 @default.
• W2019938129 creator A5058666235 @default.
• W2019938129 creator A5070135040 @default.
• W2019938129 date "1978-02-01" @default.
• W2019938129 modified "2023-10-18" @default.
• W2019938129 title "Electron spectroscopy studies of the chemisorption of O2, H2 and H2O on the TiO2(100) surfaces with varied stoichiometry: Evidence for the photogeneration of Ti+3 and for its importance in chemisorption" @default.
• W2019938129 cites W1975681319 @default.
• W2019938129 cites W1981320405 @default.
• W2019938129 cites W2000228691 @default.
• W2019938129 cites W2003354419 @default.
• W2019938129 cites W2004899614 @default.
• W2019938129 cites W2025886488 @default.
• W2019938129 cites W2030359336 @default.
• W2019938129 cites W2062602228 @default.
• W2019938129 cites W283640366 @default.
• W2019938129 doi "https://doi.org/10.1016/0039-6028(78)90328-x" @default.
• W2019938129 hasPublicationYear "1978" @default.
• W2019938129 type Work @default.
• W2019938129 sameAs 2019938129 @default.
• W2019938129 citedByCount "258" @default.
• W2019938129 countsByYear W20199381292012 @default.
• W2019938129 countsByYear W20199381292013 @default.
• W2019938129 countsByYear W20199381292014 @default.
• W2019938129 countsByYear W20199381292015 @default.
• W2019938129 countsByYear W20199381292016 @default.
• W2019938129 countsByYear W20199381292017 @default.
• W2019938129 countsByYear W20199381292018 @default.
• W2019938129 countsByYear W20199381292019 @default.
• W2019938129 countsByYear W20199381292020 @default.
• W2019938129 countsByYear W20199381292021 @default.
• W2019938129 countsByYear W20199381292022 @default.
• W2019938129 countsByYear W20199381292023 @default.
• W2019938129 crossrefType "journal-article" @default.
• W2019938129 hasAuthorship W2019938129A5051920789 @default.
• W2019938129 hasAuthorship W2019938129A5058666235 @default.
• W2019938129 hasAuthorship W2019938129A5070135040 @default.
• W2019938129 hasConcept C100083437 @default.
• W2019938129 hasConcept C113196181 @default.
• W2019938129 hasConcept C120665830 @default.
• W2019938129 hasConcept C121332964 @default.
• W2019938129 hasConcept C127413603 @default.
• W2019938129 hasConcept C144082473 @default.
• W2019938129 hasConcept C146088050 @default.
• W2019938129 hasConcept C147789679 @default.
• W2019938129 hasConcept C150394285 @default.
• W2019938129 hasConcept C162711632 @default.
• W2019938129 hasConcept C171250308 @default.
• W2019938129 hasConcept C175708663 @default.
• W2019938129 hasConcept C178187954 @default.
• W2019938129 hasConcept C179104552 @default.
• W2019938129 hasConcept C185544564 @default.
• W2019938129 hasConcept C185592680 @default.
• W2019938129 hasConcept C192562407 @default.
• W2019938129 hasConcept C207114421 @default.
• W2019938129 hasConcept C25442681 @default.
• W2019938129 hasConcept C2779070497 @default.
• W2019938129 hasConcept C33790079 @default.
• W2019938129 hasConcept C33893257 @default.
• W2019938129 hasConcept C42360764 @default.
• W2019938129 hasConcept C43617362 @default.
• W2019938129 hasConcept C51286037 @default.
• W2019938129 hasConcept C77557913 @default.
• W2019938129 hasConcept C9950777 @default.
• W2019938129 hasConceptScore W2019938129C100083437 @default.
• W2019938129 hasConceptScore W2019938129C113196181 @default.
• W2019938129 hasConceptScore W2019938129C120665830 @default.
• W2019938129 hasConceptScore W2019938129C121332964 @default.
• W2019938129 hasConceptScore W2019938129C127413603 @default.
• W2019938129 hasConceptScore W2019938129C144082473 @default.
• W2019938129 hasConceptScore W2019938129C146088050 @default.
• W2019938129 hasConceptScore W2019938129C147789679 @default.
• W2019938129 hasConceptScore W2019938129C150394285 @default.
• W2019938129 hasConceptScore W2019938129C162711632 @default.
• W2019938129 hasConceptScore W2019938129C171250308 @default.
• W2019938129 hasConceptScore W2019938129C175708663 @default.
• W2019938129 hasConceptScore W2019938129C178187954 @default.
• W2019938129 hasConceptScore W2019938129C179104552 @default.
• W2019938129 hasConceptScore W2019938129C185544564 @default.
• W2019938129 hasConceptScore W2019938129C185592680 @default.
• W2019938129 hasConceptScore W2019938129C192562407 @default.
• W2019938129 hasConceptScore W2019938129C207114421 @default.
• W2019938129 hasConceptScore W2019938129C25442681 @default.
• W2019938129 hasConceptScore W2019938129C2779070497 @default.
• W2019938129 hasConceptScore W2019938129C33790079 @default.
• W2019938129 hasConceptScore W2019938129C33893257 @default.
• W2019938129 hasConceptScore W2019938129C42360764 @default.
• W2019938129 hasConceptScore W2019938129C43617362 @default.
• W2019938129 hasConceptScore W2019938129C51286037 @default.
• W2019938129 hasConceptScore W2019938129C77557913 @default.
• W2019938129 hasConceptScore W2019938129C9950777 @default.
• W2019938129 hasIssue "2" @default.
• W2019938129 hasLocation W20199381291 @default.
• W2019938129 hasOpenAccess W2019938129 @default.
• W2019938129 hasPrimaryLocation W20199381291 @default.
• W2019938129 hasRelatedWork W1992015951 @default.
• W2019938129 hasRelatedWork W1997354715 @default.

• next