FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019939023> ?p ?o ?g. }

• W2019939023 endingPage "201" @default.
• W2019939023 startingPage "183" @default.
• W2019939023 abstract "The reduction of RhCl3 - 3 H2O by sodium amalgam in THF solution under an atmosphere of N2 and in the presence of an excess of a phosphine ligand has resulted in the formation of the hydridodinitrogen complexes RhH(N2)-(PPh(t-Bu)2)2 (I), RhH(N2)(P(t-Bu)3)2 (II), and [RhH(P(cyclo-C6H11)3)2]2(μ-N2)(V), and a hydridotrisphosphine complex RhH(P(i-Pr)3)3 (X). The dinitrogen coordination is stable in I but N2 is readily lost from other dinitrogen complexes, permitting the isolation of three-coordinate hydridobisphosphine rhodium(I) complexes RhH(P(t-Bu)3)2 (VII) and RhH(P(cyclo-C6H11)3)2 (VIII). Trihydrido complexes RhH3L2 (L = PPh(t-Bu)2 (XI), P(t-Bu)3 (XII), P(cyclo-C6H11)2 (XIII), and P(i-Pr)3 (XIV)) have been synthesized by the reaction of the above rhodium (I) compounds with H2. By treatment of the corresponding trihydrido complexes with N2 we have been able to obtain RhH(N2)-(P(cyclo-C6H11)3)2 (III) and RhH(N2)(P(i-Pr)3)2 (IV). Loss of N2 from IV results in the formation of [RhH(P(i-Pr)3)2]2(μ-N2) (VI) and RhH(P(i-Pr)3)2 (IX). The crystal and molecular structure of [RhH(P(i-Pr)3)2]2(μ-N2) (VI) has been determined at —85°C. The compound crystallizes in the triclinic space group CP1 with two molecules in a cell dimensions a 12.703(16), b 16.455(16), c 11.389(8) Å, α 90.25(9), β 103.87(3), γ 97.58(3)°, V 2289 Å3. The final conventional and weighted agreement indices on Fo for Fo2τ3σ(Fo2) are 0.051 and 0.060, respectively. The dinitrogen ligand of VI linearly bridges two planar RhHP2 fragments with NN separation of 1.134(5) Å and an average RhN bond distance of 1.977(6) Å. The dihedral angle between the two RhHP2 fragments is 55.2°. Overall, the dimeric complex effectively has D2 (222) symmetry." @default.
• W2019939023 created "2016-06-24" @default.
• W2019939023 creator A5011348851 @default.
• W2019939023 creator A5015454414 @default.
• W2019939023 creator A5029356303 @default.
• W2019939023 creator A5048877350 @default.
• W2019939023 creator A5065642690 @default.
• W2019939023 creator A5073418131 @default.
• W2019939023 date "1979-11-01" @default.
• W2019939023 modified "2023-09-25" @default.
• W2019939023 title "Preparations and reactions of some hydridodinitrogentrialkylphosphine complexes of rhodium(i). The structure of a dinitrogen-bridged rhodium(i) dimer, [RhH(P(i-Pr)3)2]2(μ-N2)" @default.
• W2019939023 cites W1535976998 @default.
• W2019939023 cites W1964042355 @default.
• W2019939023 cites W1968588096 @default.
• W2019939023 cites W1977428129 @default.
• W2019939023 cites W1981670886 @default.
• W2019939023 cites W1984456904 @default.
• W2019939023 cites W1985060667 @default.
• W2019939023 cites W1998022725 @default.
• W2019939023 cites W1998325074 @default.
• W2019939023 cites W2002524851 @default.
• W2019939023 cites W2015143184 @default.
• W2019939023 cites W2015784886 @default.
• W2019939023 cites W2022440614 @default.
• W2019939023 cites W2022755811 @default.
• W2019939023 cites W2024784916 @default.
• W2019939023 cites W2025170160 @default.
• W2019939023 cites W2027229813 @default.
• W2019939023 cites W2027956271 @default.
• W2019939023 cites W2028900655 @default.
• W2019939023 cites W2033475436 @default.
• W2019939023 cites W2033872102 @default.
• W2019939023 cites W2042757704 @default.
• W2019939023 cites W2049850818 @default.
• W2019939023 cites W2061692632 @default.
• W2019939023 cites W2066015634 @default.
• W2019939023 cites W2071391426 @default.
• W2019939023 cites W2071851122 @default.
• W2019939023 cites W2077610104 @default.
• W2019939023 cites W2090788492 @default.
• W2019939023 cites W2091702998 @default.
• W2019939023 cites W2102699586 @default.
• W2019939023 cites W2132075068 @default.
• W2019939023 cites W2146349054 @default.
• W2019939023 cites W2147318047 @default.
• W2019939023 cites W2150899448 @default.
• W2019939023 cites W2151592003 @default.
• W2019939023 cites W2168808369 @default.
• W2019939023 cites W2319007066 @default.
• W2019939023 cites W2325701523 @default.
• W2019939023 cites W2330961991 @default.
• W2019939023 cites W2480059917 @default.
• W2019939023 cites W2949108817 @default.
• W2019939023 cites W2951136067 @default.
• W2019939023 cites W2951950567 @default.
• W2019939023 cites W2952355584 @default.
• W2019939023 cites W2953269064 @default.
• W2019939023 cites W3005427594 @default.
• W2019939023 cites W3024373342 @default.
• W2019939023 cites W344804745 @default.
• W2019939023 cites W4232913275 @default.
• W2019939023 doi "https://doi.org/10.1016/s0022-328x(00)85748-4" @default.
• W2019939023 hasPublicationYear "1979" @default.
• W2019939023 type Work @default.
• W2019939023 sameAs 2019939023 @default.
• W2019939023 citedByCount "52" @default.
• W2019939023 countsByYear W20199390232014 @default.
• W2019939023 countsByYear W20199390232017 @default.
• W2019939023 countsByYear W20199390232019 @default.
• W2019939023 countsByYear W20199390232020 @default.
• W2019939023 countsByYear W20199390232022 @default.
• W2019939023 crossrefType "journal-article" @default.
• W2019939023 hasAuthorship W2019939023A5011348851 @default.
• W2019939023 hasAuthorship W2019939023A5015454414 @default.
• W2019939023 hasAuthorship W2019939023A5029356303 @default.
• W2019939023 hasAuthorship W2019939023A5048877350 @default.
• W2019939023 hasAuthorship W2019939023A5065642690 @default.
• W2019939023 hasAuthorship W2019939023A5073418131 @default.
• W2019939023 hasConcept C115624301 @default.
• W2019939023 hasConcept C116569031 @default.
• W2019939023 hasConcept C155647269 @default.
• W2019939023 hasConcept C161790260 @default.
• W2019939023 hasConcept C170493617 @default.
• W2019939023 hasConcept C178790620 @default.
• W2019939023 hasConcept C185592680 @default.
• W2019939023 hasConcept C2777716191 @default.
• W2019939023 hasConcept C2779546866 @default.
• W2019939023 hasConcept C42228675 @default.
• W2019939023 hasConcept C521398313 @default.
• W2019939023 hasConcept C55493867 @default.
• W2019939023 hasConcept C71240020 @default.
• W2019939023 hasConcept C8010536 @default.
• W2019939023 hasConceptScore W2019939023C115624301 @default.
• W2019939023 hasConceptScore W2019939023C116569031 @default.
• W2019939023 hasConceptScore W2019939023C155647269 @default.
• W2019939023 hasConceptScore W2019939023C161790260 @default.
• W2019939023 hasConceptScore W2019939023C170493617 @default.
• W2019939023 hasConceptScore W2019939023C178790620 @default.

• next