Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019941117> ?p ?o ?g. }
- W2019941117 abstract "Abstract Three heterospin complexes [M(NIT4Py)2(cda)H2O] (M = Cu(II) (1), Ni(II) (2), Co(II) (3)) with various paramagnetic 3d metal ions and pyridyl-substituted nitronyl nitroxide radical (NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide, H2cda = 4-hydroxy-pyridine-2,6-dicarboxylic acid) have been synthesized, characterized structurally and magnetically. The single crystal structures show that complexes 1–3 are isomorphic, and have 2D supramolecular network consisting of [M(NIT4Py)2(cda)H2O] with three paramagnetic centers. The magnetic measurements indicated that complexes 1–3 exhibit all antiferromagnetic interactions between M(II) and radicals with JCu–rad = −7.30 cm−1, JNi–rad = −3.58 cm−1 and JCo–rad = −1.85 cm−1, respectively. Their magnetic behaviors were interpreted in terms of the spin polarization mechanism of the π-electrons of NIT4Py and the orthogonality of 3d magnetic orbital of M(II) ion and the 2pπ orbital on the pyridine rings of NIT4Py." @default.
- W2019941117 created "2016-06-24" @default.
- W2019941117 creator A5012152127 @default.
- W2019941117 creator A5023016175 @default.
- W2019941117 creator A5037415051 @default.
- W2019941117 creator A5047629787 @default.
- W2019941117 creator A5066767193 @default.
- W2019941117 creator A5075943848 @default.
- W2019941117 creator A5078786088 @default.
- W2019941117 creator A5088179485 @default.
- W2019941117 creator A5091735030 @default.
- W2019941117 date "2013-03-01" @default.
- W2019941117 modified "2023-09-27" @default.
- W2019941117 title "Synthesis, crystal structures and magneto-structural correlations study of three 3d metal–radical heterospin complexes" @default.
- W2019941117 cites W1511407547 @default.
- W2019941117 cites W1965179197 @default.
- W2019941117 cites W1971487418 @default.
- W2019941117 cites W1974725586 @default.
- W2019941117 cites W1978269357 @default.
- W2019941117 cites W1982577591 @default.
- W2019941117 cites W1984156950 @default.
- W2019941117 cites W1990774222 @default.
- W2019941117 cites W1993048142 @default.
- W2019941117 cites W1995343225 @default.
- W2019941117 cites W1999528505 @default.
- W2019941117 cites W1999598381 @default.
- W2019941117 cites W2001882850 @default.
- W2019941117 cites W2003767748 @default.
- W2019941117 cites W2004368355 @default.
- W2019941117 cites W2005452848 @default.
- W2019941117 cites W2012789783 @default.
- W2019941117 cites W2014464561 @default.
- W2019941117 cites W2022327079 @default.
- W2019941117 cites W2025621395 @default.
- W2019941117 cites W2029461575 @default.
- W2019941117 cites W2035160040 @default.
- W2019941117 cites W2049720037 @default.
- W2019941117 cites W2050847749 @default.
- W2019941117 cites W2054563042 @default.
- W2019941117 cites W2055610469 @default.
- W2019941117 cites W2055613577 @default.
- W2019941117 cites W2062682639 @default.
- W2019941117 cites W2064625011 @default.
- W2019941117 cites W2066364185 @default.
- W2019941117 cites W2073681231 @default.
- W2019941117 cites W2075493048 @default.
- W2019941117 cites W2076355953 @default.
- W2019941117 cites W2079207006 @default.
- W2019941117 cites W2083670310 @default.
- W2019941117 cites W2083885008 @default.
- W2019941117 cites W2084857033 @default.
- W2019941117 cites W2089740902 @default.
- W2019941117 cites W2105683687 @default.
- W2019941117 cites W2113541659 @default.
- W2019941117 cites W2122741560 @default.
- W2019941117 cites W2135374860 @default.
- W2019941117 cites W2144417274 @default.
- W2019941117 cites W2149550684 @default.
- W2019941117 cites W2156398353 @default.
- W2019941117 cites W2331263697 @default.
- W2019941117 cites W2951589754 @default.
- W2019941117 cites W2952993688 @default.
- W2019941117 doi "https://doi.org/10.1016/j.ica.2012.11.013" @default.
- W2019941117 hasPublicationYear "2013" @default.
- W2019941117 type Work @default.
- W2019941117 sameAs 2019941117 @default.
- W2019941117 citedByCount "4" @default.
- W2019941117 countsByYear W20199411172015 @default.
- W2019941117 countsByYear W20199411172016 @default.
- W2019941117 countsByYear W20199411172017 @default.
- W2019941117 crossrefType "journal-article" @default.
- W2019941117 hasAuthorship W2019941117A5012152127 @default.
- W2019941117 hasAuthorship W2019941117A5023016175 @default.
- W2019941117 hasAuthorship W2019941117A5037415051 @default.
- W2019941117 hasAuthorship W2019941117A5047629787 @default.
- W2019941117 hasAuthorship W2019941117A5066767193 @default.
- W2019941117 hasAuthorship W2019941117A5075943848 @default.
- W2019941117 hasAuthorship W2019941117A5078786088 @default.
- W2019941117 hasAuthorship W2019941117A5088179485 @default.
- W2019941117 hasAuthorship W2019941117A5091735030 @default.
- W2019941117 hasConcept C111998727 @default.
- W2019941117 hasConcept C115624301 @default.
- W2019941117 hasConcept C121332964 @default.
- W2019941117 hasConcept C124712363 @default.
- W2019941117 hasConcept C139066938 @default.
- W2019941117 hasConcept C145148216 @default.
- W2019941117 hasConcept C155355069 @default.
- W2019941117 hasConcept C155647269 @default.
- W2019941117 hasConcept C15920480 @default.
- W2019941117 hasConcept C16889073 @default.
- W2019941117 hasConcept C169912494 @default.
- W2019941117 hasConcept C178790620 @default.
- W2019941117 hasConcept C185592680 @default.
- W2019941117 hasConcept C186927785 @default.
- W2019941117 hasConcept C26873012 @default.
- W2019941117 hasConcept C2779485729 @default.
- W2019941117 hasConcept C521977710 @default.
- W2019941117 hasConcept C544153396 @default.
- W2019941117 hasConcept C8010536 @default.
- W2019941117 hasConcept C82217956 @default.