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- W2019941681 endingPage "776" @default.
- W2019941681 startingPage "770" @default.
- W2019941681 abstract "The reactivity of CO2 and COS with divalent and trivalent organosamarium complexes has been investigated. (C5Me5)2Sm(THF)2 reductively couples CO2 in THF at room temperature to form the oxalate complex, [(C5Me5)2Sm]2(μ-η2:η2-O2CCO2), 1, in >90% yield. The metal centers in 1 are formally eight-coordinate. The reaction of COS with (C5Me5)2Sm(THF)2 is more complicated and generates a disproportionation product, (C5Me5)2Sm(μ-η2:η1-S2CO)Sm(C5Me5)2(THF), 2, which has one (C5Me5)2Sm unit involved in a four-membered ring, while the other (C5Me5)2Sm unit is bound to THF and the oxygen of the S2CO ligand. CO2 reacts with [(C5Me5)2Sm]2(μ-η1:η1-N2Ph2) in >90% yield to form the asymmetrical monoinsertion product, (C5Me5)2Sm[μ-η2:η1-PhNN(CO2)Ph]Sm(C5Me5)2(THF), 3. One (C5Me5)2Sm unit is involved in a five-membered ring, and the other is attached to THF and the other oxygen originating from CO2. 1−3 were characterized by analytical methods, X-ray diffraction, and NMR and IR spectroscopy." @default.
- W2019941681 created "2016-06-24" @default.
- W2019941681 creator A5011086784 @default.
- W2019941681 creator A5056791963 @default.
- W2019941681 creator A5089479056 @default.
- W2019941681 date "1998-02-05" @default.
- W2019941681 modified "2023-10-12" @default.
- W2019941681 title "Organosamarium-Mediated Transformations of CO<sub>2</sub> and COS: Monoinsertion and Disproportionation Reactions and the Reductive Coupling of CO<sub>2</sub> to [O<sub>2</sub>CCO<sub>2</sub>]<sup>2-</sup>" @default.
- W2019941681 cites W1511429944 @default.
- W2019941681 cites W1808402910 @default.
- W2019941681 cites W1966729480 @default.
- W2019941681 cites W1966912581 @default.
- W2019941681 cites W1967831353 @default.
- W2019941681 cites W1969685774 @default.
- W2019941681 cites W1969987704 @default.
- W2019941681 cites W1972856246 @default.
- W2019941681 cites W1973639779 @default.
- W2019941681 cites W1981141489 @default.
- W2019941681 cites W1985088132 @default.
- W2019941681 cites W1985235311 @default.
- W2019941681 cites W1985969829 @default.
- W2019941681 cites W1987802280 @default.
- W2019941681 cites W1990239861 @default.
- W2019941681 cites W1990852473 @default.
- W2019941681 cites W1991069230 @default.
- W2019941681 cites W1991071828 @default.
- W2019941681 cites W1992721461 @default.
- W2019941681 cites W1993191439 @default.
- W2019941681 cites W1993322056 @default.
- W2019941681 cites W1994015921 @default.
- W2019941681 cites W1994819998 @default.
- W2019941681 cites W2001766927 @default.
- W2019941681 cites W2008872937 @default.
- W2019941681 cites W2010252868 @default.
- W2019941681 cites W2011341872 @default.
- W2019941681 cites W2013090324 @default.
- W2019941681 cites W2018256404 @default.
- W2019941681 cites W2018854995 @default.
- W2019941681 cites W2020012774 @default.
- W2019941681 cites W2020561818 @default.
- W2019941681 cites W2021571036 @default.
- W2019941681 cites W2022274057 @default.
- W2019941681 cites W2024750866 @default.
- W2019941681 cites W2026556266 @default.
- W2019941681 cites W2026792423 @default.
- W2019941681 cites W2027627851 @default.
- W2019941681 cites W2029263206 @default.
- W2019941681 cites W2030160323 @default.
- W2019941681 cites W2030436151 @default.
- W2019941681 cites W2030927400 @default.
- W2019941681 cites W2032590691 @default.
- W2019941681 cites W2033327084 @default.
- W2019941681 cites W2033347230 @default.
- W2019941681 cites W2035866334 @default.
- W2019941681 cites W2038821228 @default.
- W2019941681 cites W2040747943 @default.
- W2019941681 cites W2043641174 @default.
- W2019941681 cites W2048600325 @default.
- W2019941681 cites W2050771666 @default.
- W2019941681 cites W2052674983 @default.
- W2019941681 cites W2053885812 @default.
- W2019941681 cites W2058911059 @default.
- W2019941681 cites W2061677431 @default.
- W2019941681 cites W2062283855 @default.
- W2019941681 cites W2065726478 @default.
- W2019941681 cites W2071614883 @default.
- W2019941681 cites W2073686188 @default.
- W2019941681 cites W2074440834 @default.
- W2019941681 cites W2076480576 @default.
- W2019941681 cites W2077954215 @default.
- W2019941681 cites W2078834576 @default.
- W2019941681 cites W2079136053 @default.
- W2019941681 cites W2079685234 @default.
- W2019941681 cites W2081204399 @default.
- W2019941681 cites W2084791441 @default.
- W2019941681 cites W2088924643 @default.
- W2019941681 cites W2091085928 @default.
- W2019941681 cites W2092387342 @default.
- W2019941681 cites W2092973850 @default.
- W2019941681 cites W2094017246 @default.
- W2019941681 cites W2096233197 @default.
- W2019941681 cites W2097246264 @default.
- W2019941681 cites W2105565769 @default.
- W2019941681 cites W2120710909 @default.
- W2019941681 cites W2125517342 @default.
- W2019941681 cites W2128179591 @default.
- W2019941681 cites W2162091238 @default.
- W2019941681 cites W2162316554 @default.
- W2019941681 cites W2163194823 @default.
- W2019941681 cites W2163820192 @default.
- W2019941681 cites W2357224822 @default.
- W2019941681 cites W2492645956 @default.
- W2019941681 cites W2829234832 @default.
- W2019941681 cites W2949533998 @default.
- W2019941681 cites W2950749413 @default.
- W2019941681 cites W2950934288 @default.
- W2019941681 cites W2952029999 @default.
- W2019941681 cites W2952531196 @default.