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- W2019947603 abstract "The reaction of 1,6-diaminohexane monohydroperchlorate with acetone gives Me6[22]dieneN4· 2HClO4† in high yield (ca.85%). Reaction of the diene with NaBH4 in methanol gives a mixture of C-meso Me6[22]aneN4†† (m.p. 128 °C) and C-racemic Me6[22]aneN4 (m.p. 75 °C) which can be separated by fractional crystallisation from hot xylene. The free base form of Me6[22]dieneN4 has been characterised and molecular weight measurements by vapour pressure osmometry confirm the 22-membered ring structure. The ligands give binuclear methoxy-bridged complexes of the type [M2L(OCH3)2](ClO4)2 with metal ions such as copper(II) and nickel(II) L = C-meso Me6[22]aneN4 or Me6[22]dieneN4)." @default.
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- W2019947603 date "1985-04-01" @default.
- W2019947603 modified "2023-09-23" @default.
- W2019947603 title "Complexes of large ring macrocycles. The preparation of Me6[22]dieneN4, C-meso Me6[22]aneN4, C-racemic Me6[22]aneN4 and some binuclear copper(II) and nickel(II) complexes" @default.
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- W2019947603 doi "https://doi.org/10.1016/s0020-1693(00)86051-x" @default.
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