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- W2019949957 abstract "Arene(phosphane)metal Complexes, XII. Unexpected Formation of Monohydrido(phosphane)osmium(II) Complexes C6H6OsH[PMe2(OR)]I from C6H6Os(PMe2H)I2. A Compound with an OsPMe2 Bond as Intermediate?The reaction of [C6H6OsI2]2 (4) with PMe2H produces the compound C6H6Os(PMe2H)I2 (5) which reacts with KO-t-C4H9 in methanol or diethylamine to give the monohydrido-(phosphane)osmium(II) complexes C6H6OsH[PMe2(OR)]I (6a, RCH3; 6b, Rt-C4H9). The mechanism possibly involves the formation of an intermediate 7 containing an OsPMe2 bond." @default.
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- W2019949957 date "1986-06-01" @default.
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- W2019949957 title "Aromaten(phosphan)metall‐Komplexe, XII. Unerwartete Bildungsweise der Monohydrido(phosphan)‐osmium(II)‐Komplexe C <sub>6</sub> H <sub>6</sub> OsH[PMe <sub>2</sub> (OR)]I aus C <sub>6</sub> H <sub>6</sub> Os(PMe <sub>2</sub> H)I <sub>2</sub> . Eine Verbindung mit einer OsPMe <sub>2</sub> ‐Bindung als Zwischenstufe?" @default.
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- W2019949957 doi "https://doi.org/10.1002/cber.19861190625" @default.
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