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- W2019957012 abstract "Chemical retention, i.e., partition of the element between aqueous solution and mineral surface, is a key phenomenon for assessing the safety of possible nuclear waste disposal. For this purpose, the sorption of Eu(III) onto a model mineral—α-alumina—is studied here, including the effects of groundwater chemistry: pH and concentrations of small organic and inorganic ligands (acetate, oxalate, and carbonate anions). This work presents some experimental evidence for a synergic mechanism of sorption of europium–ligand complexes onto the alumina. Only cationic complexes were necessary to consider to model experimental results. Using the ion-exchange theory (IET) and a corresponding restricted set of parameters—exchange capacities and thermodynamic equilibrium constants—the whole set of sorption experiments of Eu(III) cationic species onto the α-alumina was modeled under various chemical conditions." @default.
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- W2019957012 date "2006-06-01" @default.
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- W2019957012 title "Effect of aqueous acetic, oxalic, and carbonic acids on the adsorption of europium(III) onto α-alumina" @default.
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- W2019957012 doi "https://doi.org/10.1016/j.jcis.2006.01.004" @default.
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