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• W2019957149 startingPage "69" @default.
• W2019957149 abstract "Modified polynomial energy gap law (PEGL) and exponential energy gap law (EGL) have been fitted on a set of line broadening coefficients. This set of values has been recently obtained by high-resolution inverse Raman spectroscopy and covers a wide temperature range and a great number of Q(J) rotational lines. A consistent description of the J and temperature dependences of linewidth is obtained from the two considered laws. These laws together with the general expression of the SRS profile permit a predictive synthetization of the collisionally narrowed Q-branch for pressures up to 35 atm. An excellent reproduction of the observed spectra is evidenced by using the EGL model if the collisional lineshifts of the Q(J) components are accounted for. This model is applicable to high temperature, the simulation of SRS or CARS spectra requiring only the knowledge of the lineshift's temperature dependence." @default.
• W2019957149 created "2016-06-24" @default.
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• W2019957149 date "1987-07-01" @default.
• W2019957149 modified "2023-10-03" @default.
• W2019957149 title "Study of rotational relaxation fitting laws from calculations of SRS N2 Q-branch" @default.
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• W2019957149 doi "https://doi.org/10.1016/0301-0104(87)80179-9" @default.
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