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- W2019958961 abstract "γ-Cyclodextrin (γ-CyD) was hydrophobically modified by selective functionalization at the C-6 position (primary face) with fluoroalkyl ester groups. This new amphiphilic γ-CyD was prepared in a facile one-pot synthesis by direct esterification of γ-CyD with perfluorobutanoic acid on the narrow rim of macrocylic molecule. The selective per-substituted product, octakis (6-O-perfluorobutanoyl)-γ-cyclodextrin (γ-CyD-F), was confirmed by 1H NMR, 13C NMR and 19F NMR spectroscopic methods. The complexing ability of the γ-CyD-F was investigated with different types of anionic surfactant having single or double hydrophobic tail groups. Predominant complex formation was observed in all cases with an equimolar mixture of surfactant and γ-CyD-F in methanol irrespective of the type of the surfactant." @default.
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- W2019958961 date "2006-06-01" @default.
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- W2019958961 title "A facile one-pot synthesis of novel amphiphilic perfluoroalkyl ester functionalized γ-cyclodextrin and complex formation with anionic surfactants" @default.
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- W2019958961 doi "https://doi.org/10.1016/j.jfluchem.2006.02.004" @default.
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