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- W2019959418 abstract "The reduction of easily available methyl 5,6-dihydro-4H-1,2-oxazin-3-ylacetates provides an efficient route to different diastereomerically pure unnatural β-amino acids. A two-step protocol including reduction of the C=N bond of the initial oxazine with sodium cyanoborohydride during the first step and hydrogenation of the N-O bond during the second step produced the target β-amino acid esters with higher stereoselectivity than obtained with conventional catalytic hydrogenation." @default.
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- W2019959418 date "2009-06-26" @default.
- W2019959418 modified "2023-09-27" @default.
- W2019959418 title "Stereoselective Synthesis of Unnatural β-Amino Acids from Nitroethane via 5,6-Dihydro-4H-1,2-oxazin-3-ylacetates" @default.
- W2019959418 doi "https://doi.org/10.1055/s-0029-1216872" @default.
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