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• W2019959887 abstract "With a nitro-functionalized dicarboxylate ligands, the title Cu(II) compound contains cross-packed supramolecular ladders formed via hydrogen bonding and π–π interactions, while the Mn(II) compound exhibits a 3D pcu framework based on Mn 3 (COO) 6 clusters, for which magnetic analyses are performed based not only on temperature-dependent susceptibilities but also on field-dependent magnetizations. Two new metal–organic coordination polymers with 1,5-dinitronaphthalene-3,7-dicarboxylate (NNDC), [Cu 2 (NNDC) 2 (DMF) 1.8 (DMSO) 2.2 (H 2 O) 2 ]·H 2 O (1) and [Mn 3 (NNDC) 3 (DMSO) 4 ]·2DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O–H⋯O hydrogen bonds and π–π interactions, and the ladders are packed in a cross fashion through further π–π interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the pcu topology, in which [Mn 3 (COO) 6 ] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn 3 (COO) 6 ] cluster." @default.
• W2019959887 created "2016-06-24" @default.
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• W2019959887 date "2010-08-01" @default.
• W2019959887 modified "2023-10-14" @default.
• W2019959887 title "Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with 1,5-dinitronaphthalene-3,7-dicarboxylate" @default.
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• W2019959887 doi "https://doi.org/10.1016/j.ica.2010.04.011" @default.
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