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- W2019960650 abstract "Redox dynamics of manganese (Mn) were studied in the sediment of Lake Zurich using precise sediment core age models, monthly long-term oxygen (O2) monitoring data of the water column (1936–2010) and high-resolution XRF core scanning. The age models were based on bi-annual lamination and calcite precipitation cycles. If present, Mn exhibits distinct maxima, which coincide with the annual maximum deep-water O2 concentrations in spring according to the monitoring data. In contrast, the iron (Fe) signal is mainly the result of calcite dilution, as indicated by a strong negative correlation between Fe and calcium (Ca) XRF data. The Mn/Fe ratio in the core from the maximum lake depth (ZH10-15, 137 m) revealed a moderate correlation with O2 measurements in the lake bottom water confirming the successful application of the Mn/Fe ratio to semi-quantitatively reconstruct bottom water oxygenation in the lake. Mostly low ratios were observed between 1895 and the mid-1960s as a result of eutrophication. However, geochemical focusing and sedimentological factors can reduce the applicability of the Mn/Fe ratio in reconstructing O2 concentrations in the bottom water of lakes." @default.
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- W2019960650 date "2013-08-01" @default.
- W2019960650 modified "2023-10-03" @default.
- W2019960650 title "Tracing bottom water oxygenation with sedimentary Mn/Fe ratios in Lake Zurich, Switzerland" @default.
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- W2019960650 doi "https://doi.org/10.1016/j.chemgeo.2013.06.006" @default.
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