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- W2019964243 abstract "The reaction of NaNO2 in acidic solution with thiocarbonyl compounds has been studied. Secondary- and tertiary thioamides, 1-benzyl-hexahydro-2H-azepine-2-thione, 5-ethyl-5-phenyl thiobarbituric acid, certain thiourea derivatives, 2H-1-benzopyran-2-thione, O,O-diphenyl-thiocarbonic ester, O,S-diphenyl-dithiocarbonic ester, N,N-dimethyl-S-phenyl-dithiocarbamatic ester, N-ethyl-N-phenyl-O-ethyl-thiocarbamatic ester are all converted into the corresponding carbonyl-analogues. 4,4′-Bis (dimethylamino)-thiobenzophenone (Michler's thioketone) gives 3-nitro-4,4′-bis (dimethylamino)-benzophenone at room temperature. At (−10 °C)-(−5 °C) the expected oxo compound is obtained as the main product together with 4-(N-nitroso-methylamino)-4′-(dimethylamino)-benzophenone." @default.
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- W2019964243 date "1982-01-01" @default.
- W2019964243 modified "2023-10-18" @default.
- W2019964243 title "The transformation using the soft NO⊕-species" @default.
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- W2019964243 doi "https://doi.org/10.1016/0040-4020(82)85099-0" @default.
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