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- W2019965362 abstract "There is experimental evidence that intermediate ortho-benzynes can be made by intramolecular [2 + 4] cycloaddition of a 1,3-diyne with an alkyne. Computations by several groups support a concerted mechanism for the cycloaddition of butadiyne with acetylene. High temperature benzyne cycloreversion has also been demonstrated experimentally; this may in fact be a common reaction in hydrocarbon fuel combustion. Following leads from earlier pyrolysis experiments, herein we predict that cycloaddition of benzyne with butadiyne can proceed by a stepwise mechanism to 2,3-naphthyne. However, a slightly lower energy path leads to a benzocyclobutadiene. ortho-Benzyne can be generated by solution-phase and solid-phase reaction in a microwave reactor. We have developed the method of microwave flash pyrolysis (MFP) for high temperature solid-phase microwave reactions. MFP reaction of phthalic anhydride, a classic benzyne precursor, results in a typical suite of products expected from a relatively high concentration of benzyne." @default.
- W2019965362 created "2016-06-24" @default.
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- W2019965362 creator A5047100448 @default.
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- W2019965362 date "2010-01-01" @default.
- W2019965362 modified "2023-09-24" @default.
- W2019965362 title "New Thermal Routes to ortho-Benzyne" @default.
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- W2019965362 doi "https://doi.org/10.1071/ch10074" @default.
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