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- W2019968172 abstract "Complexes of composition CuL 4 (EF 6 ) 2 (where L is pyridine, 3-methylpyridine, or 4-methylpyridine and E is P or As) have been prepared and characterized by epr, electronic and infrared spectroscopic, and magnetic susceptibility studies. Results are consistent with elongated tetragonal–octahedral structures with coordinated anions. The coordinating strength of PF 6 − is estimated to be less than that of AsF 6 − and both are considered weaker than perchlorate. Analysis of the epr data indicates significant metal to heterocyclic ligand π-electron delocalization, the extent and nature of which depends on the orientation of the heterocyclic ring in the CuL 4 chromophore. Analysis of infrared data suggests that the intensities of the v 1 and v 2 vibrations as they occur in EF 6 − complexes generally provide an indication of the strength of metal–anion interactions." @default.
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- W2019968172 date "1982-04-15" @default.
- W2019968172 modified "2023-10-10" @default.
- W2019968172 title "Magnetic and spectroscopic studies of structure and bonding in hexafluorophosphate and hexafluoroarsenate complexes of copper(II)" @default.
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- W2019968172 doi "https://doi.org/10.1139/v82-155" @default.
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