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- W2019968334 abstract "Abstract X-ray photoelectron spectroscopy was used to determine the chemical shift and full-width at half-maximum intensity of the V 4+ and V 5+ cations peaks in the vanadium pentoxide matrix. It was found that the binding energy of V 4+ ions shifts to the lower energy side of about 1.3 eV as compared with the main V 5+ ions in the matrix. The V 2p 3/2 line width for tetravalent vanadium ions in xerogels is actually the same as for pentavalent ions. The fitting procedure of X-ray photoelectron spectra permits determination of the relative concentrations of the reduced vanadium ions with an accuracy of about 3%." @default.
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- W2019968334 date "2004-11-01" @default.
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- W2019968334 title "Determination of vanadium valence in hydrated compounds" @default.
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- W2019968334 doi "https://doi.org/10.1016/j.jallcom.2004.06.005" @default.
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