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- W2019968641 abstract "The oxidation of uranium dioxide to uranates in the ternary alkali-metal carbonate melt (Li–Na–K)2CO3 containing added chlorides or sulfates has been studied in the range 723–1023 K and a variety of uranium(VI) species was obtained. Increased oxygen solubility in fused carbonates was achieved by adding alkali-metal chloride or sulfate. The yield of uranates in chloride-containing melts decreased with increasing radius of the alkali-metal chloride cation, Li Na > K > Cs. When UO2 was oxidised in alkali chloride containing carbonate melts no intermediate uranium chloride complexes were observed. The temperature required for complete oxidation of UO2 can be lowered by 100–150 K by the addition of alkali-metal chlorides to carbonate melts. The addition of chloride and aluminium ions to form AlCl4− effected UO2 oxidation by a different mechanism, through intermediate formation of uranyl complexes, but the yield of uranates was not significantly altered. Attempts at oxidation by direct addition of potassium superoxide at 723 K were inefficient owing to thermal instability of the reagent, but UO2 oxidation was enhanced, by more than 10%, by superoxide formed insitu by the reaction of peroxide and nitrate, compared with oxidation by peroxide or nitrate individually. Optimum conditions for complete oxidation at 723 K required a peroxide:nitrate mole ratio of ca. 3. The major reaction pathway in melts containing nitrate and peroxide, at various concentrations of these reactants, was determined. At a mole ratio of oxidiser to UO2 of 0.3, the percentage of UO2 oxidised and the yield of uranates, increased in the order Na2O2 ≈ KO2 < KNO2 < KNO3 < KNO3 + Na2O2. Evidence has been obtained for a new sodium uranate, Na2O(UO3−y)x (1 < x <2 ; y < 0.02)." @default.
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- W2019968641 date "1997-01-01" @default.
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- W2019968641 title "Increased oxidation of UO2in molten alkali-metal carbonate based mixtures by increasing oxygen solubility and by controlled generation of superoxide ions, and evidence for a new sodium uranate" @default.
- W2019968641 doi "https://doi.org/10.1039/a704450j" @default.
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