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- W2019968876 abstract "The lithiation of potassium triisopropylsilylphosphanide yields the corresponding phosphanediide. The subsequent metathesis reaction with SrI2 and BaI2 in the presence of hexamethyldisiloxane gives hexalithium hexapotassium strontium hexakis(triisopropylsilylphosphanediide)bis(trimethylsilanolate) (1) and the corresponding barium derivative (2), respectively. The alkaline earth metal atoms are surrounded octahedrally by the phosphanediide ligands. Six P3 faces of the octahedron are capped by the K atoms, and the P−P edges of two opposite P3 faces are bridged by the lithium atoms. The Li cations are also bonded to the Me3SiO substituents giving a coordination number of three for the alkali metals." @default.
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- W2019968876 date "2002-12-01" @default.
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- W2019968876 title "Cage Compounds of Heterotrimetallic Mixed Phosphanediide/Silanolate Aggregates with an Alkaline Earth Metal-Centered Phosphorus Octahedron" @default.
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- W2019968876 doi "https://doi.org/10.1021/ic0202413" @default.
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