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• W2019971304 abstract "Cationic complexes of the type [M(CO)S(PPh(3))(2)](+) (M = Ir, Rh; S = CH(3)CN) react with singlet oxygen to form the corresponding peroxo complexes [M(CO)S(PPh(3))(2)(O(2))](+). The solvent molecule remains coordinated to the metal in the oxygen adducts. The novel cationic iridium-peroxo complex is stable at room temperature, while the rhodium-peroxo complex is only stable below 0 degrees C. Rate constants for physical and chemical interaction of the complexes with singlet oxygen are somewhat smaller than those for related neutral complexes. Upon addition of alkenes (tetramethylethylene or 1-octene) to the peroxo complexes, neither oxidation of the olefins nor substitution of the acetonitrile ligand was observed. 1-Octene was isomerized to give mostly 2- and 3-octene by the cationic rhodium(I) complex. A cationic iridium complex which already possesses a coordinated diene ligand ([Ir(COD)(PPh(3))(2)](+)) did not react with or quench singlet oxygen." @default.
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• W2019971304 date "1996-01-01" @default.
• W2019971304 modified "2023-10-16" @default.
• W2019971304 title "Reactions of Singlet Oxygen with Organometallic Compounds. 4. Photooxidation of Cationic Iridium(I) and Rhodium(I) Complexes with Weakly Bonded Ligands" @default.
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• W2019971304 doi "https://doi.org/10.1021/ic960056n" @default.
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