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- W2019973105 abstract "The diffusion (${mathit{D}}_{mathit{s}}$) of entangled and unentangled symmetric block copolymers is compared, above and below the ordering transition. The lamellar samples were not macroscopically oriented, and thus ${mathit{D}}_{mathit{s}}$ reflects a combination of mobilities parallel and perpendicular to the lamellar planes. For unentangled (Rouse) chains, ${mathit{D}}_{mathit{s}}$ is unaffected by the microstructure, whereas entangled (reptating) chains are retarded significantly; this difference reflects an interesting combination of thermodynamic and entanglement constraints. Furthermore, this retardation persists into the nominally disordered state." @default.
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- W2019973105 date "1993-10-18" @default.
- W2019973105 modified "2023-10-03" @default.
- W2019973105 title "Diffusion in microstructured block copolymers: Chain localization and entanglements" @default.
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- W2019973105 doi "https://doi.org/10.1103/physrevlett.71.2591" @default.
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