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- W2019973106 abstract "Diazonium ion chemistry has been used to electrochemically graft aminophenyl layers onto p-type silicon (1 0 0) substrates. A condensation reaction was used to immobilise single-walled carbon nanotubes with high carboxylic acid functionality directly to this layer. Electrochemical monitoring of the aminophenyl groups confirmed the formation of an amide linkage between the single-walled carbon nanotubes and the aminophenyl layer. The carbon nanotube electrode showed high stability and good electrochemical performance in aqueous solution. At moderate scan rates the Ru(NH3)6+3/+2 couple exhibited quasi-reversible electron transfer kinetics with a standard heterogenous rate constant of 1.2 × 10−3 cm s−1 at the covalently-linked carbon nanotube surface. The electrode thus combines the advantages of a silicon substrate for easy integration into sophisticated electrical and electronic devices, carbon nanotubes for desirable electrochemical properties, and stability in aqueous medium for future applications in environmental sensing." @default.
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- W2019973106 date "2010-04-01" @default.
- W2019973106 modified "2023-09-27" @default.
- W2019973106 title "Chemically immobilised carbon nanotubes on silicon: Stable surfaces for aqueous electrochemistry" @default.
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- W2019973106 doi "https://doi.org/10.1016/j.electacta.2010.02.046" @default.
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