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- W2019976852 abstract "Abstract FT-IR spectroscopy has been used to investigate the hydrogen-bonding systems in crystalline methyl-α- d -manno-, methyl-β- d -galacto- and methyl-α- d -glucopyranoside. The OH stretching region has been studied at subambient temperatures. Deuterium exchange has been carried out to check for vibrational coupling. Good correlation is found between the uncoupled ν OH frequency at 100 K and the ratio of OH bond length to O ⋯ O distance obtained from neutron diffraction data. This correlation can be used to assign peaks to the different OH ⋯ O systems in crystalline carbohydrates. The shift of ν OH with temperature, the wavenumber-temperature coefficient (WTc), also proves to be useful in the assignment." @default.
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- W2019976852 title "Hydrogen bonds in crystalline carbohydrates A variable-temperature FT-IR study" @default.
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- W2019976852 doi "https://doi.org/10.1016/0022-2860(94)08233-2" @default.
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