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• W2019978452 abstract "Two new mixed ligand copper(II) complexes with diethylenetriamine, 2,2'-bipyridine and 1,10-phenanthroline have been synthesized. The crystal and molecular structures of [Cu(dien)(phen)](ClO(4))(2) and [Cu(dien)(bipy)](BF(4))(2) (dien=diethylenetriamine, phen=1,10-phenanthroline, bipy=2,2'-bipyridine) were determined by X-ray crystallography from single crystal data. These two complexes have similar structures. The EPR spectral data also suggest that these complexes have distorted square pyramidal geometry about copper(II). Anti-microbial and superoxide dismutase activities of these complexes have also been measured. They show the higher SOD activity than the corresponding simple Cu(II)-dien/Cu(II)-PMDT (PMDT=N,N,N',N',N''-pentamethyldiethylenetriamine) complexes because of a strong axial bond of one of the nitrogen atoms of the alpha-diimine. Both the complexes have been found to cleave plasmid DNA in the presence of co-reductants such as ascorbic acid and glutathione." @default.
• W2019978452 created "2016-06-24" @default.
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• W2019978452 date "2005-11-01" @default.
• W2019978452 modified "2023-09-26" @default.
• W2019978452 title "Characterization and biological activities of two copper(II) complexes with diethylenetriamine and 2,2′-bipyridine or 1,10-phenanthroline as ligands" @default.
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• W2019978452 doi "https://doi.org/10.1016/j.saa.2004.12.034" @default.
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