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- W2019978762 abstract "The photolysis of ethoxalyl azide gives ethoxalylnitrene and ethoxycarbonyl isocyanate. The nitrene adds to C=C double bonds and is inserted into O–H and C–H bonds. At high ethanol concentrations, where the singlet nitrene predominates, the O–H insertion product is formed dominantly. At low ethanol concentrations, where much of the nitrene changes to the triplet state, the hydrogen-abstraction product is preferred. The reactivity of the nitrene toward the C–H bonds of 2-methylbutane is more selective than that of ethoxycarbonylnitrene." @default.
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- W2019978762 date "1972-12-01" @default.
- W2019978762 modified "2023-09-26" @default.
- W2019978762 title "Photolyses of Ethoxalyl Azide in Alcohols and in Hydrocarbons Reactions of Ethoxalylnitrene" @default.
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