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- W2019985689 abstract "Durch Polymerisation in Substanz wurden Copolymere aus Trioxan und Glycidyläthern ein- und zweiwertiger Alkohole oder Phenole, Butylvinyläther, 1.3-Dioxolan und Styrol hergestellt. Die Bildung übermolekularer Strukturen bei der Kristallisation aus dünnen Schmelzfilmen wurde mikroskopisch untersucht. Es ergab sich, daß die Copolymeren mit nur aliphatischen comonomeren Bausteinen als typische Hedrite kristallisieren. Die durch Polymerisation von Trioxan in Gegenwart von gemischten aliphatisch-aromatischen Monomeren erhaltenen Copolymeren neigen bei isothermer und besonders bei nichtisothermer Kristallisation zur Bildung intermediärer hedritisch-sphärolithischer oder sphärolithischer Strukturen. Trioxane copolymers were synthesized by bulk polymerization with glycidyl ethers of monovalent and divalent alcohols and phenols, butylvinylether, 1.3-dioxolane and styrene. The structure formation during their crystallization was investigated from a thin melted film by means of an optical microscope. It was found that the crystallization of those copolymers with entirely aliphatic comonomer units was typically hedrite. obtained by the polymerization of trioxane in the presence of monomers of mixed aliphatic-aromatic character have a tendency to form hedrite-spherolite or spherolite structures of intermediate character during the isothermic and mainly during the non-isothermic crystallization." @default.
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- W2019985689 date "1969-12-05" @default.
- W2019985689 modified "2023-09-26" @default.
- W2019985689 title "Strukturbildung von trioxancopolymeren" @default.
- W2019985689 doi "https://doi.org/10.1002/macp.1969.021290120" @default.
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