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• W2019989909 abstract "A detailed vibrational spectrum of trimethylthallium is reported for the first time (Raman spectra of the melt and crystal, IR spectra of crystalline, gaseous and matrix-isolated samples). Analogous data were also obtained for trimethylindium for comparison. In the Raman spectra of both compounds in the liquid state some peculiarities are found which suggest low-barrier hindered rotation of the methyl groups. Some features in the spectra of trimethylthallium and triethylthallium distinguish these compounds from their In and Ga analogues, and could be interpreted as arguments in favour of distortion of the planar TIC3 skeleton in condensed phases, probably as a result of the pseudo-Jahn—Teller effect." @default.
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• W2019989909 date "1997-05-01" @default.
• W2019989909 modified "2023-10-03" @default.
• W2019989909 title "Vibrational spectra and structure of trimethylindium and trimethylthallium" @default.
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• W2019989909 doi "https://doi.org/10.1016/s0022-328x(96)06793-9" @default.
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