Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019991569> ?p ?o ?g. }
- W2019991569 endingPage "9882" @default.
- W2019991569 startingPage "9876" @default.
- W2019991569 abstract "This paper reports on the electrochemical behavior of bovine insulin at the interface between two immiscible electrolyte solutions (ITIES). The voltammetric ion-transfer response obtained in the presence of insulin was dependent on the aqueous phase pH conditions and on the nature of the organic phase electrolyte employed in experiments. Optimal detection was obtained at acidic pH below the isoelectric point of insulin where it was positively charged. A shift in transfer potentials to lower potential values was observed with decreasing hydrophobicity of the anion of the organic phase electrolyte. No ion-transfer response was observed at pH values of the aqueous phase above the isoelectric point, where insulin was negatively charged. These results suggest that the voltammetric response is due to ion-pairing interactions at the ITIES between positively charged insulin and the hydrophobic anion of the organic phase electrolyte, together with adsorption of the ion-pair at the interface. The voltammetric response was obtained for insulin at concentrations down to 1 μM. These results show that electrochemistry is useful in studying the behavior of this important protein molecule at the polarized water−1,2-DCE interface and provides an alternative detection mode for bioanalytical applications." @default.
- W2019991569 created "2016-06-24" @default.
- W2019991569 creator A5045973904 @default.
- W2019991569 creator A5077627198 @default.
- W2019991569 creator A5079094578 @default.
- W2019991569 date "2008-07-31" @default.
- W2019991569 modified "2023-10-10" @default.
- W2019991569 title "Electrochemical Study of Insulin at the Polarized Liquid−Liquid Interface" @default.
- W2019991569 cites W1881789240 @default.
- W2019991569 cites W1967695848 @default.
- W2019991569 cites W1969502959 @default.
- W2019991569 cites W1971894551 @default.
- W2019991569 cites W1972614182 @default.
- W2019991569 cites W1972838124 @default.
- W2019991569 cites W1974794078 @default.
- W2019991569 cites W1975681845 @default.
- W2019991569 cites W1977109465 @default.
- W2019991569 cites W1977333361 @default.
- W2019991569 cites W1977666417 @default.
- W2019991569 cites W1978423478 @default.
- W2019991569 cites W1978876908 @default.
- W2019991569 cites W1986593058 @default.
- W2019991569 cites W1987368594 @default.
- W2019991569 cites W1988089093 @default.
- W2019991569 cites W1988089792 @default.
- W2019991569 cites W1988244143 @default.
- W2019991569 cites W2003763606 @default.
- W2019991569 cites W2003899611 @default.
- W2019991569 cites W2004567559 @default.
- W2019991569 cites W2007166916 @default.
- W2019991569 cites W2010059646 @default.
- W2019991569 cites W2017303495 @default.
- W2019991569 cites W2017469587 @default.
- W2019991569 cites W201794922 @default.
- W2019991569 cites W2020267609 @default.
- W2019991569 cites W2021899336 @default.
- W2019991569 cites W2022767334 @default.
- W2019991569 cites W2029380002 @default.
- W2019991569 cites W2030326663 @default.
- W2019991569 cites W2035669105 @default.
- W2019991569 cites W2037315589 @default.
- W2019991569 cites W2039256659 @default.
- W2019991569 cites W2040919342 @default.
- W2019991569 cites W2043761562 @default.
- W2019991569 cites W2044268482 @default.
- W2019991569 cites W2044590574 @default.
- W2019991569 cites W2048685643 @default.
- W2019991569 cites W2050272137 @default.
- W2019991569 cites W2050732618 @default.
- W2019991569 cites W2051547691 @default.
- W2019991569 cites W2052228268 @default.
- W2019991569 cites W2058294391 @default.
- W2019991569 cites W2064457936 @default.
- W2019991569 cites W2066785113 @default.
- W2019991569 cites W2067855344 @default.
- W2019991569 cites W2071028216 @default.
- W2019991569 cites W2072257037 @default.
- W2019991569 cites W2073456429 @default.
- W2019991569 cites W2076915463 @default.
- W2019991569 cites W2077147390 @default.
- W2019991569 cites W2079125485 @default.
- W2019991569 cites W2080449381 @default.
- W2019991569 cites W2080764717 @default.
- W2019991569 cites W2086855104 @default.
- W2019991569 cites W2087891320 @default.
- W2019991569 cites W2097000867 @default.
- W2019991569 cites W2151309411 @default.
- W2019991569 cites W2154950066 @default.
- W2019991569 cites W2169065069 @default.
- W2019991569 cites W2316778497 @default.
- W2019991569 cites W2322540009 @default.
- W2019991569 cites W3122152400 @default.
- W2019991569 cites W4231001873 @default.
- W2019991569 cites W4254405998 @default.
- W2019991569 cites W964503500 @default.
- W2019991569 doi "https://doi.org/10.1021/la800842f" @default.
- W2019991569 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18666786" @default.
- W2019991569 hasPublicationYear "2008" @default.
- W2019991569 type Work @default.
- W2019991569 sameAs 2019991569 @default.
- W2019991569 citedByCount "84" @default.
- W2019991569 countsByYear W20199915692012 @default.
- W2019991569 countsByYear W20199915692013 @default.
- W2019991569 countsByYear W20199915692014 @default.
- W2019991569 countsByYear W20199915692015 @default.
- W2019991569 countsByYear W20199915692016 @default.
- W2019991569 countsByYear W20199915692017 @default.
- W2019991569 countsByYear W20199915692018 @default.
- W2019991569 countsByYear W20199915692019 @default.
- W2019991569 countsByYear W20199915692020 @default.
- W2019991569 countsByYear W20199915692021 @default.
- W2019991569 countsByYear W20199915692022 @default.
- W2019991569 countsByYear W20199915692023 @default.
- W2019991569 crossrefType "journal-article" @default.
- W2019991569 hasAuthorship W2019991569A5045973904 @default.
- W2019991569 hasAuthorship W2019991569A5077627198 @default.
- W2019991569 hasAuthorship W2019991569A5079094578 @default.
- W2019991569 hasConcept C113196181 @default.