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- W2019992168 abstract "A novel type of supramolecular poly(azomethine) was synthesized by the polycondensation of an inclusion complex of β-cyclodextrin/poly(oxypropylene)diamine with one of β-cyclodextrin/terephthaldehyde and a subsequent reaction with [60]fullerene as the end capping agent. Molar mass determination by gel permeation chromatography showed that the polymers had a high molar mass (about 150 kg · mol−1) with a very narrow polydispersity. Isothermal titration calorimetric studies confirmed that each poly-(oxypropylene)diamine unit could host seven cyclodextrin molecules, which was further supported by 1H NMR spectroscopy and molecular modeling studies. Additional characterization by 13C NMR and FT-IR spectroscopy, as well as by thermogravimetric analysis, confirmed the structure of the cyclodextrin-based polyrotaxane." @default.
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- W2019992168 date "2007-09-11" @default.
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- W2019992168 title "Poly(azomethine) Rotaxanes: Novel Water Soluble Supramolecular Polymers with High Molar Mass" @default.
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