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- W2019996246 abstract "Branching ratios for the fragmentation of 16O2+ and 18O2+ molecular cations initially prepared in their b−4Σg− ν = 0–5 and B2Σg − ν = 0–5 vibronic states by direct ionization (He(1α)radiation) are reported. For the b−4∑g− ν = 0–5 vibronic states of 16O2+, the extent of competition between the emission process b−4Σg− — a−4Πu and predissociation is found to be in good agreement with the literature. New data for the b −4Σg− electronic state of 18O2+ are obtained. The ν = 3–5 vibrational levels of the B2Σg− electronic state of both isotopic species are shown to decay competitively via the fragmentation channels O+ (4S)+O(3P and O− (4S)+O(1D. The suggestion that at the ionization energy of the B2Σg− ν = 4 vibronic state of 16O2+ a curve-crossing between the 2Σg− and presumably a 4Πg potential curve takes place is corroborated." @default.
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- W2019996246 date "1982-07-01" @default.
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- W2019996246 title "Predissociation of the molecular oxygen cations 16O2+ and 18O2+ studied by photoelectron-photoion coincidence spectroscopy" @default.
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- W2019996246 doi "https://doi.org/10.1016/0020-7381(82)80008-9" @default.
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