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• W2019998240 endingPage "191" @default.
• W2019998240 startingPage "177" @default.
• W2019998240 abstract "Abstract Kinetics of transient photocurrents caused by the electron transfer (ET) reactions in weakly polar solvents is computed on the assumption that ions are formed by dissociation of exciplexes, the primary product of the ET reactions. The rise time of the photocurrent arising from the time dependent polarization of geminate solvated ion pairs in the applied electric field is shown to be less than the fluorescence decay time of exciplexes, the precursors of the ions. The obtained time dependence of the photocurrent agrees well with the photoconductivity traces in the solutions of 9,10-dicyanoanthracene and durene observed by Zhou et al. [J. Zhou, B.R. Findley, T.M. Francis, E.A. Nytko, C.L. Braun, Chem. Phys. Lett. 362 (2002) 63–71; J. Zhou, R.P. Shah, B.R. Findley, C.L. Braun, J. Phys. Chem. A 106 (2002) 12–20]. Their interpretation of the experimental data rests on the alternative assumption that free ions are generated not from exciplexes but from solvent-separated ion pairs originally produced on the ET quenching of the excited states of 9,10-dicyanoanthracene by durene. However, the performed analysis of the photocurrent kinetics supports the conclusion that ions arise by dissociation of exciplexes." @default.
• W2019998240 created "2016-06-24" @default.
• W2019998240 creator A5050328624 @default.
• W2019998240 date "2007-06-01" @default.
• W2019998240 modified "2023-09-29" @default.
• W2019998240 title "Kinetics of transient photocurrents arising from dissociation of exciplexes in solutions at times comparable to the diffusion separation time of geminate ion pairs" @default.
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• W2019998240 doi "https://doi.org/10.1016/j.jphotochem.2007.01.029" @default.
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