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- W2020004877 abstract "The new organotin compound, Ph 2 Sn(Cl)[S(C 7 H 3 N 2 O 2 S)]·[(C 7 H 3 N 2 O 2 S)OEt], assembled by an intermolecular aromatic benzothiazolebenzothiazole π-π stacking interaction, has been synthesized by the reaction of diphenyltin dichloride with 2-mercapto-6-nitrobenzothiazole. The title compound was characterized by elemental, IR, 1 H NMR, and X-ray crystallography analyses. Single-crystal X-ray diffraction data reveals that the title compound has two different molecular components. The component Ph 2 Sn(Cl)[S(C 7 H 3 N 2 O 2 S)] has a pentacoordinate tin, which further forms an infinite one-dimensional chain by intermolecular non-bonded Cl···S interactions, resulting in an intercalation lattice that holds (C 7 H 3 N 2 O 2 S)OEt molecules. The formation of the molecule (C 7 H 3 N 2 O 2 S)OEt as well as its intercalated mechanism has also been discussed.Key words: organotin, assemble, π-π stacking interaction, 2-mercapto-6-nitrobenzothiazole, non-bonded interaction, crystal structure." @default.
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- W2020004877 date "2003-07-01" @default.
- W2020004877 modified "2023-09-25" @default.
- W2020004877 title "Synthesis and characterization of a linked, π-π stacked organotin compound of 2-mercapto-6-nitrobenzothiazolyl diphenyltin chloride with 2-ethoxyl-6-nitrobenzothiazole" @default.
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- W2020004877 doi "https://doi.org/10.1139/v03-087" @default.
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