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• W2020005654 abstract "Organic crystals are likely to have a large degree of structural relaxation near their surfaces because of the weak inter-molecular interactions. The design of organic field-effect transistors requires a detailed knowledge of the surface relaxation as the carriers usually transfer within the first few molecular layers at the semiconductor surfaces, and their transport properties reflect the structural changes through the transfer integral. Here, we report the direct observation of the surface relaxation of an organic semiconductor, a tetracene single crystal, by means of X-ray crystal truncation rod scattering measurements. A significant degree of surface relaxation is observed, taking place only in the first monolayer at the semiconductor surface. First principles calculations show that the resultant transfer integrals are completely different between the bulk and surface of the semiconductor." @default.
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• W2020005654 date "2014-11-07" @default.
• W2020005654 modified "2023-10-09" @default.
• W2020005654 title "Large surface relaxation in the organic semiconductor tetracene" @default.
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• W2020005654 doi "https://doi.org/10.1038/ncomms6400" @default.
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