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- W2020010461 abstract "The Raman spectra in the region of the O-H stretching vibration band are used to investigate the effect of lanthanide (III) ions on liquid water structure in concentrated aqueous solutions of CeCl3 and GdCl3 (C∼0.5÷3 M). The differential spectra, derived from the consequent Raman spectra, have reflected the substantial discrepancy between the spectra of lanthanide (III) salt solutions and pure water as well as the spectra of standard LiCl (C∼1.5÷9M) solutions. The new sharp bands (vmax ∼ 3180÷3190 cm−1) and (vmax∼3360 cm−1), observed in the differential spectra, are assumed to two types of aqua-ions: Ln3+[H2O]mH2On and Ln3+[H2O]mClp− having a difference in the 2nd coordination sphere. The discrepancy, observed in the spectra of the equmolar CeCl3 and GdCl3 aqueous solutions, is interpreted as a result of the different hydration numbers and ion radiuses of Ce3+aq and Gd3+aq." @default.
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- W2020010461 date "2011-04-01" @default.
- W2020010461 modified "2023-10-06" @default.
- W2020010461 title "Raman spectroscopic study of trivalent lanthanides in concentrated aqueous solutions" @default.
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- W2020010461 doi "https://doi.org/10.1088/1742-6596/289/1/012012" @default.
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