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• W2020021403 endingPage "480" @default.
• W2020021403 startingPage "476" @default.
• W2020021403 abstract "The activation of tris(dimethylamino)borane towards reaction with a chiral methimazole by N-methylimidazole has been used to prepare the first example of a chiral tris(methimazolyl)borate ligand. Coordination of this neutral ligand to Ru(II) has been achieved by reaction with [(p-cymene)RuCl(2)](2) to provide a single diastereomer complex in which the chirality of the methimazolyl substituents dictate the chirality of the bicyclo[3.3.3]cage formed by the ligand on coordination to the metal. The alternative approach to chiral tris(methimazolyl)borate ligands involving the introduction of a chiral group onto the boron atom has been explored by replacing N-methylimidazole in the above reaction by chiral oxazolines as activating bases in reaction with simple methimazole. However, although the B(NMe(2))(3) is activated to reaction with methimazole by these oxazolines, an intramolecular oxazoline ring-opening by a coordinated methimazolyl sulfur occurs and prevents the successful synthesis of these ligands." @default.
• W2020021403 created "2016-06-24" @default.
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• W2020021403 creator A5080639435 @default.
• W2020021403 date "2007-01-01" @default.
• W2020021403 modified "2023-10-14" @default.
• W2020021403 title "Tripodal borate ligands from tris(dimethylamino)borane: the first synthesis of a chiral tris(methimazolyl)borate ligand, and the crystal structure of a single diastereomer pseudo-C₃-symmetric Ru(<scp>ii</scp>) complex" @default.
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• W2020021403 doi "https://doi.org/10.1039/b611331a" @default.
• W2020021403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17213933" @default.
• W2020021403 hasPublicationYear "2007" @default.
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