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• W202003155 abstract "The partitioning and adsorption mechanisms of retention in reversed-phase liquid chromatography (RPLC) were examined based on the free energy of transfer of a methylene group from organic aqueous mixtures to bulk hexadecane. Retention on monomeric bonded phases with octyl chains or longer are dominated by a partitioning-like mechanism. An adsorption-like mechanism contributes to retention in monomeric bonded phases with short bonded chains or with low surface coverage density. The retention mechanism becomes more adsorption-like as the length of the bonded chains decrease." @default.
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• W202003155 date "1997-07-01" @default.
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• W202003155 title "Revisionist look at solvophobic driving forces in reversed-phase liquid chromatography" @default.
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• W202003155 doi "https://doi.org/10.1016/s0021-9673(97)00228-8" @default.
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